Avoir is used with most verbs.
Être is used with:
Movement verbs: aller, venir, arriver, partir, entrer, sortir, monter, descendre, tomber, passer, retourner
aller, venir, arriver, partir, entrer, sortir, monter, descendre, tomber, passer, retourner
State changes: naître, mourir, devenir, rester
naître, mourir, devenir, rester
Reflexive verbs: se lever, se laver...
se lever, se laver...